The following state regulations pages link to this page. (iii) the primary class, which may be shown as a number only or under the heading Class or Classe or following the word Class or Classe. WebListing, classification and packing Mercury (UN 2809): Subsidiary risk 6.1 Transmitted by the expert from Germany Introduction 1. How does the consignor determine the classification for a dangerous good? The subsidiary class is the other class that further identifies the hazards of the dangerous goods. A proof of classification is a document that the consignor must provide, upon request, to the federal Minister of Transport. Determine the shipping name: Check if the product name is listed in Schedule 1 or Schedule 3. This placard is not mandatory, but it is permitted on a large means of containment (greater than 450 L) instead of any other placard when the containment has: - one or more dangerous goods that require different hazard class placards, - the dangerous goods are contained in two or more small means of containment, AND - the shipment consists of only the following dangerous goods classified in: NOTE: The TDG Regulations has specified circumstances when this placard is not allowed to be used. Powdered metals. For hazardous mixtures or other articles, it takes more efforts and expertise to determine an accurate UN number and proper shipping name. ), code or number for a particular hazard (e.g., 1- Explosive, 2 - Gases, 3 - Flammables), Provide quick identification of the dangerous goods in an emergency (e.g., release of dangerous goods during an incident), Communicate the nature and degree of the danger, Quickly determine if dangerous goods in a mixed load are incompatible, is determined to be a dangerous good under the TDG Regulations, and, displayed against a background of contrasting colour, made of durable, weather-resistant material that will resist coming detached or fade, Select the correct label(s) for each small means of containment (e.g., drum, package, overpack), Make sure that each small means of containment (e.g., package or container) of dangerous goods is properly labelled and marked, Select the correct placards and other safety marks for each large means of containment (e.g., tanker), Display the placards and other safety marks, or provide the appropriate placards to the carrier (when the means of containment or means of transport belongs to the carrier), Confirm that the safety marks are correct, Make sure the safety marks are displayed and remain displayed during transport, Replace safety marks when during transport they are stolen, lost, or defaced, Provide and display appropriate safety marks when the contents of the shipment change (e.g., new consignments are loaded on the means of transport), Remove or cover safety marks when the dangerous good is no longer present. Some of the classes can be further divided into divisions, e.g., Class 1, while others do not have sub-divisions, e.g., Class 3. As per subsection 11.1(1) of the TDG Regulations, the IMDG Code must be consulted for international transport by ship. The type of packages must be indicated by description of the package (for example, 12 drums). You may experience longer than usual wait times or partial service interruptions. Are there any exemptions for placards? See Column 4 in Schedule 1. I, II or III) assigned to the substance or article. (iii) For domestic shipments, primary and subsidiary hazard class or division names may be entered following the numerical hazard class or division, or following the basic description. However, if the dangerous goods are explosive, the consignor must use the classification determined by the Natural Resources Canada. A placard is used for a large means of containment whose capacity is more than 450 L. The marks for safety for each TDG class are shown in the OSH Answers document Transportation of Dangerous Goods (TDG) - 9 Classes. The type of packaging and destination marks may be entered in any appropriate manner before or after the basic description. More than one subsidiary class is possible. The number of placards depends on the type of large means of containment, classification of the dangerous good, and the type safety mark that is required. How many placards are required on a large means of containment? The Proper Shipping Name shall be supplemented with "MOLTEN"; Stabilized substances: The following provisions also apply: (i) For Class 1 materials, the quantity must be the net explosive mass. When a consolidation bin is used, the class of each dangerous good contained in the bin must be marked on a tag or on a fixed display device that is attached to the bin. Select country for which that subsidiary belongs to. Determine the primary class, subsidiary class(es) and packing group by using section 2.8 - Precedence of Classes in Part 2, Classification. endstream endobj 1274 0 obj <>/Metadata 31 0 R/Pages 1271 0 R/StructTreeRoot 36 0 R/Type/Catalog>> endobj 1275 0 obj <>/MediaBox[0 0 612 792]/Parent 1271 0 R/Resources<>/Font<>/ProcSet[/PDF/Text/ImageB/ImageC/ImageI]/XObject<>>>/Rotate 0/StructParents 0/Tabs/S/Type/Page>> endobj 1276 0 obj <>stream "R}~Q:~pgg'"l/O:OV~ @zo7g;)K;=d'}z8}7w7?Iuw?w~ikK^^'d4k;g_u_LOC6($uiz["Dw#b{ogw~0B"ty'{~Oi"v?`"DqXmImPiww#R{;?j}J3]0{ ?>]|YlbE#SsBsz/E":}NCg7ON2P5N}s/w?9LO?zZ^/1BWu~N"r~!P;1FAS*:hzQHo _+3l3E6FAsmH}]fwcxoCcbb,!7cTvt{o&h: foC"uF2c;&4m;vx?=8 ga ` !%6M`Wn-@lM;#={CSaW+r:&|gB7/ndJlXqFxs1}n]N:=jd#]5$b{9NF">OL_7!y;3~*cQlCek4o6 eeGn:9P_mO}W'^q7{X,V{TFi8Qj eg/od{QVg{*Ky3n_0ht vv@9g;OkRz~w}79!^C:[7C .{;T/tUOB9x|]\;Q7W{!~uhM See Section 2.4. ?O.Q\tF,"V4Iuu8jhb7ew?NI ~eS^lsEU_{\3>e; F]u:MvF7Bz3Jz;O>tzw5qy:!&|]&$fG6F`B@a'\` Eno14}tQ`?K4%1nFh,D_Qg4f>~j $7NH s:o~P;v4fRd%r{6|;>v&K >Z!O~X}u!wv=@~0}$vN=. Can I use a UN number that is not included in the Canadian TDG Regulations? 1 0 obj Self-heating solid, toxic, organic, n.o.s. Placard for the subsidiary hazard class (if any) next to the primary hazard class placard on each side and each end (total of four) for: Each dangerous good that must have an ERAP. Classification is defined in Part 1 of the TDG Regulations as: classification means, for dangerous goods, as applicable, the shipping name, the primary class, the An appropriate modifier, such as contains or containing, and/or the percentage of the technical constituent may also be used. Mercury is an element and a metal that is found in air, water, and soil. If the product's name is listed only in Schedule 3, use the UN number from Column 3 in this schedule to look up the product in Schedule 1. We expect this update to take about an hour. For example, both gasoline and diesel are listed by their name in Schedule 1. Code R. Ch. Note 3: The containers inside the package not required to bear TDG safety marks. If a substance is included in more than one class or packing group, its classification is determined in the following manner: Based on the definition for classification, a competent person must determine the following before a classification can be assigned to a dangerous good: Use all three schedules as listed in the TDG Regulations. Browse our full range of workplace health and safety products and services. % Founded in 1961 and headquartered in Los Angeles, Mercury has assets in excess of $4 billion, employs 4,500 people and has more than 8,000 independent agents in 11 states (Arizona, California, What is the purpose of dangerous goods safety marks? In this case, the product is not TDG regulated and the product does not need to comply with the TDG Regulations. Mercury's surface temperatures are That legal outcome opened the door to hire a new design and construction team to finish the North Course. 1. Generic risk (e.g., flammable, toxic, etc.). /Producer(Sub Systems, Inc.)/CreationDate(D:20211224145622+05'00')/ModDate(D:20211224145622+05'00')/Creator(Sub Systems, Inc.) Proper shipping name is the standard technical name to describethe hazard properties and the composition of dangerous goods. Electronic Code of Federal Regulations (e-CFR), Subtitle B - Other Regulations Relating to Transportation, CHAPTER I - PIPELINE AND HAZARDOUS MATERIALS SAFETY ADMINISTRATION, DEPARTMENT OF TRANSPORTATION, SUBCHAPTER C - HAZARDOUS MATERIALS REGULATIONS, PART 172 - HAZARDOUS MATERIALS TABLE, SPECIAL PROVISIONS, HAZARDOUS MATERIALS COMMUNICATIONS, EMERGENCY RESPONSE INFORMATION, TRAINING REQUIREMENTS, AND SECURITY PLANS, Ariz. Admin. Primary Class This column gives the primary class of the dangerous goods. It would be shipped as "UN 2809, MERCURY, 8(6.1)" and assigned to Packing Group II. Indication of the packaging specification number (1H1) may be included in the description of the package (for example, 12 1H1 drums or 12 drums (UN 1A1)). The data below is an example showing UN1203, GASOLINE. will be unavailable during this time. Peroxides. means Not Otherwise Specified. Note 2: Package certification safety marks are specified in the standard that the package or container is compliant with. For example, the shipping name for a mixture that consists of 80% gasoline and 20% diesel will be: FLAMMABLE LIQUID, N.O.S. How do I determine the compatibility group? You need to ask yourself the following questions first and follow the above rules to determine accurate proper shipping names for your products. Admin. The size (i.e., capacity) of the means of containment itself also determines whether a label or placard is required. You can Explosives 2. WebClassifying Substances That Are Included in More Than One Class or Packing Group The Primary class is shown first, with the subsidiary classes in brackets. hmk0`oW,PIl/J_hH ]lwY8>Kwg"e.RN B 4$&ECI* pZN6'4pI %;=KzU?_ojW{tO&1>I4ZeQ6gVO5"_|v"8[UD A label is used for a small means of containment whose capacity is 450 L or less. WebThe symbol P used in this schedule means that the handling, offering for transport, and transporting of the dangerous goods by rail is prohibited. Note: This document is a general overview of the TDG classification requirements. (7) The number and type of packages must be indicated. Flammable Gases 3. Laboratory tests are required for pure substances, solutions, and mixtures. Regulatory information United States of America Inventory Component CAS-No TSCA TSCA Inventory notification - Active/Inactive TSCA - EPA Regulatory Flags Mercury Leave the safety marks on a large means of containment until the means of containment is cleaned or purged. (UN3291). Note that these types of products do not have a UN Number. Admin. 1. NOTE: The table below is for guidance purposes only. We do not provide consultancy services. From the surface of Mercury, the Sun would appear more than three times as large as it does when viewed from Earth, and the sunlight would be as much as seven times brighter. For example, based on the above information from Schedule 1 we have the following information for UN1203: Schedules 1 and 3 will also indicate if any shipping routes are forbidden. (5) Except for transportation by aircraft, the total quantity of hazardous materials covered by the description must be indicated (by mass or volume, or by activity for Class 7 materials) and must include an indication of the applicable unit of measurement, for example, 200 kg (440 pounds) or 50 L (13 gallons). It can cause headaches, can damage the nervous system of the body. The following packing group always takes precedence irrespective of hazards: The following hazard class always takes precedence irrespective of packing groups: If above two rules do not apply, please refer to the following hazard precedence table to choose primary hazard. Figure 2: Safety marks on a small means of containment such as a package Note 1: The orientation marks for liquids are optional for road transport, but mandatory for air transport. If two or more dangerous goods have different UN numbers but are identified by the same placard or placards, the placard is required to be displayed only once on each side and on each end of a large means of containment regardless of how many products in the large means of containment have that class (primary or subsidiary) [See Section 4.15 in the TDG Regulations]. Alkalis. WebClass 1 Explosives; Class 2 Gases; Class 3 Flammable liquids; Class 4 Other Flammable Substances; Class 5 Oxidizing Substances & Organic Peroxides; Class 6 Code Regs. WebIdentification Product Name Mercury (Certified ACS) Cat No. If the dangerous goods are biohazardous substances (Class 6.2), the consignor may use the classification determined by Health Canada or the Canadian Food Inspection Agency. Flash point: UN Number This column gives the UN number assigned to the dangerous goods under the UN system. This mark must be displayed on one side of a means of containment. The solution or mixture is mentioned by name in the Dangerous Goods List; The name mentioned only applies to the pure substance; The hazard class or division, subsidiary risk, packing group or physical state of the mixture or solution is different from that of the substance mentioned; The hazard characteristics and properties of the mixture require different emergency response measures; Is it a pure substance or well-defined mixture (by use) or well-defined article? Code 246-231-140 - 246-231-140 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. In response, we have issued some transportation-related measures and guidance. Subsidiary classes are provided in brackets and are only listed in Column 3 of Schedule 1 (not Schedule 3). Regs. The required markings for overpacks include: Placards are not required for consolidation bins as the definition and description for a consolidation bin does not include large means of containment. Dangerous good: gross mass is 500 kg or less. The rules are set out in a table, the segregation table in 7.2.4, and also have to be applied in respect of any subsidiary class. >> Substances (including substances and mixtures), and articles are assigned to one of the following 9 classes according to the most predominant hazards they pose in transport. No. Inorganic mercury compounds. Azides. Except for combustible liquids, the subsidiary hazard class(es) or subsidiary division number(s) must be entered in parentheses immediately following the primary hazard class or division number. ; UN 1992, FLAMMABLE LIQUID, TOXIC, N.O.S. Information on compatibility groups is provided in Appendix 2 of Part 2 in the TDG Regulations. Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. The labels must be displayed on two opposite sides of the outer surface of a small means of containment. What information is needed for classification? Who is responsible for classifying a dangerous good? Code 5-3-25.4 - 410 IAC 5-3-25.4 - Advance notice of transport of nuclear waste, Kan. Admin. The Primary class is shown first, with the subsidiary classes in brackets. 0 Consult Schedule 3 for the shipping name that most precisely describes the dangerous goods. a document that explains how the dangerous goods were classified. Code 3701:1-50-23 - 3701:1-50-23 - Advance notification of shipment of irradiated reactor fuel and nuclear waste. Marine Pollutants: Admin. hazard class, classified in Class 6.1, Toxic substances that are listed in Special Provision 23, classified in Class 7, Radioactive materials that require a Cat III Yellow label. Note that the, classification (primary and subsidiary hazard classes), whether or not they are shipped under a TDG exemption, Label for the primary hazard class for each dangerous good in the package, Label for the subsidiary hazard class (if any) for each dangerous good in the package, Shipping name and technical name when required in Special Provision 16 in Schedule 2 of the TDG Regulations. Code 5-481-3120 - 12VAC5-481-3120 - Advance notification of transport of nuclear waste. This sign must be displayed at or next to each entry way of the large means of containment (greater than 450 L) when the containment is fumigated with a dangerous good. (contains Xylene and Benzene), 3, II. Corrosives 9. What safety marks are required on a large means of containment (capacity 450L or more)? That legal outcome opened the door to hire a new design and construction team to finish the North Course. Elevated temperature liquid, n.o.s., at or above 100C (212F) and below its flashpoint including molten metals, molten salts, etc. ; UN 1224, KETONES, LIQUID, N.O.S, Example: UN 1993 FLAMMABLE LIQUIDS, N.O.S. classified in Class 2.3, Toxic Gases hazard class, classified in Class 4.3, Water-reactive Substances hazard class and all packing groups, classified in Class 5.2, Organic Peroxides (Type B, liquid or solid, that require control temperature.) The term "MARINE POLLUTANT" shall be put in the end of dangerous goods descriptions. Have the answers at your fingertips. It is used for dangerous goods that do not have a specific entry by name in Schedule 1. It exists in several forms: Elemental (metallic) mercury. The requirements for the display of the dangerous goods safety marks also depend on: Labels and placards are diamond shaped (also referred to as square on point) and must be displayed as illustrated below. Column 6 Special Provisions If you have questions or need any help, please contact our sponsor. If the dangerous goods are radioactive, the consignor must use the classification determined by the Canadian Nuclear Safety Commission. Transport Canada is closely monitoring the COVID-19 situation. The packing group may be preceded by the letters PG (for example, PG II); and. If the dangerous good is an explosive or radioactive material, it must be classified as required by other regulatory authorities. entries are assigned with special provisions 274 or 318 (see column 6 in the example below). The following provisions also apply: (i) For empty uncleaned packaging, only the number and type of packaging must be shown; (ii) For chemical kits and first aid kits, the total net mass of hazardous materials must be shown. And how does one select a placard for different loads? If the product's name is listed in Schedule 1 or you located it by using the listed UN Number in Schedule 3, use the shipping name and its corresponding data (UN number, class, packing group/category) from that row. Image from Transport Canada. Are the classifications for other modes or international shipments the same? Perchlorates. 82-4-3k - 82-4-3k - Transportation of hazardous materials; driving and parking rules, La. Once the material has been tested at a laboratory, the test results are compared to the classification criteria in Part 2. Appendix E: Schedule 2 - List of Dangerous Goods, 6 Registration, Approvals and Certification, 8 Manufacture and Modification of Tank Cars and Ton Containers for Transport of Dangerous Goods, 9 Qualifications and Maintenance of Tank Cars and Ton Containers, 10 Selection and Use of Containers for the Handling, Offering for Transport, or Transporting of Dangerous Goods by Rail, 11 Provisions for the One Time Movement of Non-Conforming Containers Presenting Low Safety Risks, Appendix A: Procedure - Liquefied Petroleum Gas Tank Car Emission Standard, Appendix B: Procedure - Anhydrous Ammonia Tank Car Emission Standard, Appendix C: Procedures for Tank-Head Puncture-Resistance Testing, Appendix D: Procedures for Simulated Pool-Fire and Torch-Fire Testing, Appendix E: Schedule 1 - Special Provisions, transportation-related measures and guidance, Methane, compressed or Natural gas, compressed, with high methane content, Methane, refrigerated liquid or natural gas, refrigerated liquid, with high methane content, Methylacetylene and propadiene mixture, stabilized, Dangerous Goods of Class2.1, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 35% but not more than 50% ammonia, Dangerous Goods of Class2.2, not listed above, non-cryogenic, Ammonia solutions, relative density less than 0.880 at 15C (59F) in water, with more than 50% ammonia, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone B, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone C, Dangerous goods of Class 2.3, not specifically listed, meeting the definition of dangerous goods toxic by inhalation, Hazard Zone D, Dinitrogen tetroxide, or Nitrogen dioxide, Ethylene oxide or Ethylene oxide, with nitrogen, Sulphur dioxide, liquefied or Sulphur dioxide, Dangerous Goods of Class2.3, not listed above, Dimethylhydrazine, symmetrical or 1,2-Dimethylhydrazine, Organochlorine pesticide, liquid, flammable, toxic, flash point less than 23C (73F), Petroleum sour crude oil, flammable, toxic, Dangerous Goods of Class 3, Packing Group I, not listed above, Ethanol and gasoline mixture, with more than 10 percent ethanol, Organochlorine pesticide, liquid, flammable, toxic, flashpoint less than 23C (73F), Dangerous Goods of Class 3, Packing Group II, not listed above, Elevated temperature liquid, flammable, n.o.s., with flash point above 60.5C (141F), at or above its flashpoint, Dangerous Goods of Class 3, Packing Group III, not listed above, Dangerous Goods of Class4.1, Packing Group I. WebA subsidiary class placard is required to be displayed on a large means of containment for dangerous goods that requires an emergency response assistance plan (ERAP) if they the date on which the dangerous goods were classified. When tags are used, the UN number must be displayed on the primary class label or on the tag next to the primary class label. Sodium dithionite or Sodium hydrosulphite, Sodium sulphide, anhydrous or Sodium sulphide, with less than 30% water of crystallization, Dangerous Goods of Class4.2, Packing Group II, not listed above, Fibres or Fabrics, animal or vegetable or synthetic, n.o.s., with oil, Iron oxide, spent or Iron sponge, spent, obtained from hydrocarbon gas purification, Seed cake, with more than 1.5% oil and not more than 11% moisture, Seed cake, with not more than 1.5% oil and not more than 11% moisture. (a) The shipping description of a hazardous material on the shipping paper must include: (1) The identification number prescribed for the material as shown in Column (4) of the 172.101 table; (2) The proper shipping name prescribed for the material in Column (2) of the 172.101 table; (3) The hazard class or division number prescribed for the material, as shown in Column (3) of the 172.101 table. Mixed Loads: dangerous good whose gross mass is 1000 kg or less, and there are at least two different dangerous goods, and the dangerous goods are contained in at least two small means of containment inside a large means of containment. Example: UN 3082, ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. You may also find an expert in CSP business directory below. See table 1 below for placard requirements. Examples of such products are: 3. Examples: COTTON WASTE, OILY (UN1364), or REGULATED MEDICAL WASTE, N.O.S.